SAFETY DATA SHEET | Mastermix

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifiers

Product name : Nickel

Product Number : GF11019697

Brand : Aldrich

REACH No. : A registration number is not available for this substance as the

substance or its uses are exempted from registration, the

annual tonnage does not require a registration or the

registration is envisaged for a later registration deadline.

CAS-No. : 7440-02-0

1.2 Relevant identified uses of the substance or mixture and uses advised against

Identified uses : Laboratory chemicals, Manufacture of substances

1.3 Details of the supplier of the safety data sheet

Company : Mastermix GmbH

Alfred-Klingele-Str. 27-29

D-73630 Remshalden GERMANY

Telephone : +49- 7151- 97 90 3 25

Fax : +49- 7151-97 90 3 53

E-mail address : safety@mastermix.ag

1.4 Emergency telephone

Emergency Phone # : +49 (0) 172 / 710 11 660

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No 1272/2008

Skin sensitization (Category 1), H317

Carcinogenicity (Category 2), H351

Specific target organ toxicity - repeated exposure (Category 1), H372

For the full text of the H-Statements mentioned in this Section, see Section 16.

2.2 Label elements

Labelling according Regulation (EC) No 1272/2008

Pictogram

Signal Word Danger

Hazard statement(s)

H317 May cause an allergic skin reaction.

H351 Suspected of causing cancer.

H372 Causes damage to organs through prolonged or repeated exposure.

Precautionary statement(s)

P202 Do not handle until all safety precautions have been read and

understood.

P260 Do not breathe dust.

P264 Wash skin thoroughly after handling.

P280 Wear protective gloves/ protective clothing/ eye protection/

face protection.

P302 + P352 IF ON SKIN: Wash with plenty of water.

P308 + P313 IF exposed or concerned: Get medical advice/ attention.

Supplemental Hazard

Statements. none

2.3 Other hazards

This substance/mixture contains no components considered to be either persistent,

bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB)

at levels of 0.1% or higher.

SECTION 3: Composition/information on ingredients

3.1 Substances

Molecular weight : 58,69 g/mol

CAS-No. : 7440-02-0

For the full text of the H-Statements mentioned in this Section, see Section 16.

SECTION 2: Hazards identification

SECTION 4: First aid measures

4.1 Description of first-aid measures

General advice

Show this material safety data sheet to the doctor in attendance.

If inhaled

After inhalation: fresh air. Call in physician.

In case of skin contact

In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower.

Consult a physician.

In case of eye contact

After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.

If swallowed

After swallowing: immediately make victim drink water (two glasses at most). Consult a physician.

4.2 Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2.2)

and/or in section 11

4.3 Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5: Firefighting measures

5.1 Extinguishing media

Unsuitable extinguishing media For this substance/mixture no limitations of extinguishing

agents are given.

5.2 Special hazards arising from the substance or mixture

Nature of decomposition products not known. Not combustible.

5.3 Advice for firefighters

Stay in danger area only with self-contained breathing apparatus.

Prevent skin contact by keeping a safe distance or by wearing suitable

protective clothing.

5.4 Further information

Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing

water from contaminating surface

water or the ground water system.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Advice for non-emergency personnel: Avoid generation and inhalation of dusts in all

circumstances. Avoid substance contact. Ensure adequate ventilation. Evacuate the

danger area, observe emergency procedures, consult an expert.

For personal protection see section 8.

6.2 Environmental precautions

Do not let product enter drains.

6.3 Methods and materials for containment and cleaning up

Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions

(see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area.

Avoid generation of dusts.

6.4 Reference to other sections

For disposal see section 13.

SECTION 4: First aid measures

SECTION 7: Handling and storage

7.1 Precautions for safe handling

Advice on safe handling

Work under hood. Do not inhale substance/mixture.

Hygiene measures

Immediately change contaminated clothing. Apply preventive skin protection.

Wash hands and face after working with substance.

For precautions see section 2.2.

7.2 Conditions for safe storage, including any incompatibilities

Storage conditions

Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible

only to qualified or authorized persons.

Storage class

Storage class (TRGS 510): 6.1D: Non-combustible, acute toxic Cat.3 / toxic hazardous

materials or hazardous materials causing chronic effects

7.3 Specific end use(s)

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

Ingredients with workplace control parameters

8.2 Exposure controls

Personal protective equipment

Eye/face protection

Use equipment for eye protection tested and approved under appropriate

government standards such as NIOSH (US) or EN 166(EU). Safety glasses

Skin protection

This recommendation applies only to the product stated in the safety data

sheet, supplied by us and for the designated use. When dissolving in or mixing

with other substances and under conditions deviating from those stated in

EN374 please contact the supplier of CE-approved gloves

(e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0,11 mm

Break through time: 480 min

Material tested:KCL 741 Dermatril® L

Splash contact

Material: Nitrile rubber

Minimum layer thickness: 0,11 mm

Break through time: 480 min

Material tested:KCL 741 Dermatril® L

Body Protection

protective clothing

Respiratory protection

required when dusts are generated.

Our recommendations on filtering respiratory protection are based on the

following standards: DIN EN 143, DIN 14387 and other accompanying

standards relating to the used respiratory protection system. Recommended

Filter type: Filter type P3

The entrepeneur has to ensure that maintenance, cleaning and testing of

respiratory protective devices are carried out according to the instructions of

the producer. These measures have to be properly documented.

Control of environmental exposure

Do not let product enter drains.

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

a) Physical state solid

b) Color No data available

c) Odor No data available

d) Melting No data available

point/freezing point

e) Initial boiling point. No data available

and boiling range

f) Flammability (solid, gas). The product is not flammable.

g) Upper/lower. No data available

flammability or

explosive limits

h) Flash point Not applicable

i) Autoignition. No data available

temperature

j) Decomposition No data available

temperature

k) pH No data available

l) Viscosity Viscosity, kinematic: No data available

Viscosity, dynamic: No data available

m) Water solubility at 25 °C insoluble

n) Partition coefficient: Not applicable for inorganic substances

n-octanol/water

o) Vapor pressure No data available

p) Density No data available

Relative density No data available

q) Relative vapor No data available

density

r) Particle No data available

characteristics

s) Explosive properties No data available

t) Oxidizing properties none

9.2 Other safety information

No data available

SECTION 10: Stability and reactivity

10.1 Reactivity

No data available

10.2 Chemical stability

The product is chemically stable under standard ambient conditions (room temperature).

10.3 Possibility of hazardous reactions

No data available

10.4 Conditions to avoid

no information available

10.5 Incompatible materials

Strong oxidizing agents

10.6 Hazardous decomposition products

In the event of fire: see section 5

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute toxicity

LD50 Oral - Rat - male and female - > 9.000 mg/kg

(OECD Test Guideline 401)

Inhalation: No data available

Dermal: No data available

Skin corrosion/irritation

Skin - Rabbit

Result: No skin irritation - 4 h

(OECD Test Guideline 404)

Serious eye damage/eye irritation

Eyes - Rabbit

Result: No eye irritation

(OECD Test Guideline 405)

Respiratory or skin sensitization

May cause allergic skin reaction. (ECHA)

Germ cell mutagenicity

No data available

Carcinogenicity

Suspected of causing cancer.

Reproductive toxicity

No data available

Specific target organ toxicity - single exposure

No data available

Specific target organ toxicity - repeated exposure

Causes damage to organs through prolonged or repeated exposure.

Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI

(Table 3.1/3.2)

Aspiration hazard

No data available

11.2 Additional Information

Endocrine disrupting properties

Product:

Assessment : The substance/mixture does not contain

components considered to have endocrine

disrupting properties according to REACH Article

57(f) or Commission Delegated regulation (EU)

2017/2100 or Commission Regulation (EU)

2018/605 at levels of 0.1% or higher.

To the best of our knowledge, the chemical, physical, and toxicological

properties have not been thoroughly investigated.

SECTION 12: Ecological information

12.1 Toxicity

Toxicity to fish LC50 - Danio rerio (zebra fish) - > 100 mg/l - 96 h

(OECD Test Guideline 203)

Toxicity to daphnia EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h

and other aquatic

invertebrates

12.2 Persistence and degradability

The methods for determining biodegradability are not applicable to inorganic substances.

12.3 Bioaccumulative potential

No data available

12.4 Mobility in soil

No data available

12.5 Results of PBT and vPvB assessment

This substance/mixture contains no components considered to be either persistent,

bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at

levels of 0.1% or higher.

12.6 Endocrine disrupting properties

Product:

Assessment : The substance/mixture does not contain components

considered to have endocrine disrupting properties

according to REACH Article 57(f) or Commission

Delegated regulation (EU) 2017/2100 or Commission

Regulation (EU) 2018/605 at levels of 0.1% or higher.

12.7 Other adverse effects

No data available

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product

See www.retrologistik.com for processes regarding the return of chemicals and

containers, or contact us there if you have further questions.

SECTION 14: Transport information

13.1 Waste treatment methods

14.1 UN number

ADR/RID: - IMDG: - IATA: -

14.2 UN proper shipping name

ADR/RID: Not dangerous goods

IMDG: Not dangerous goods

IATA: Not dangerous goods

14.3 Transport hazard class(es)

ADR/RID: - IMDG: - IATA: -

14.4 Packaging group

ADR/RID: - IMDG: - IATA: -

14.5 Environmental hazards

ADR/RID: no IMDG Marine pollutant: no IATA: no

14.6 Special precautions for user

No data available

Further information

Not classified as dangerous in the meaning of transport regulations.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific

for the substance or mixture

This material safety data sheet complies with the requirements of Regulation

(EC) No. 1907/2006.

Authorisations and/or restrictions on use

REACH - Restrictions on the manufacture, : Nickel metal massive

placing on the market and use of certain

dangerous substances, mixtures and articles

(Annex XVII)

Other regulations

Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or

stricter national regulations where applicable.

Take note of Dir 94/33/EC on the protection of young people at work.

15.2 Chemical Safety Assessment

For this product a chemical safety assessment was not carried out

SECTION 16: Other information

Full text of H-Statements referred to under sections 2 and 3.

H317 May cause an allergic skin reaction.

H351 Suspected of causing cancer.

H372 Causes damage to organs through prolonged or repeated exposure.

Full text of other abbreviations

ADN - European Agreement concerning the International Carriage of Dangerous Goods

by Inland Waterways; ADR - Agreement concerning the International Carriage of

Dangerous Goods by Road; AIIC - Australian Inventory of Industrial Chemicals; ASTM -

American Society for the Testing of Materials; bw - Body weight; CMR - Carcinogen,

Mutagen or Reproductive Toxicant; DIN - Standard of the German Institute for

Standardisation; DSL - Domestic Substances List (Canada); ECx - Concentration

associated with x% response; ELx - Loading rate associated with x% response; EmS -

Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx -

Concentration associated with x% growth rate response; GHS - Globally Harmonized

System; GLP - Good Laboratory Practice; IARC - International Agency for Research on

Cancer; IATA - International Air Transport Association; IBC - International Code for the

Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half

maximal inhibitory concentration; ICAO - International Civil Aviation Organization;

IECSC - Inventory of Existing Chemical Substances in China; IMDG - International

Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial

Safety and Health Law (Japan); ISO - International Organisation for Standardization;

KECI - Korea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a

test population; LD50 - Lethal Dose to 50% of a test population (Median Lethal Dose);

MARPOL - International Convention for the Prevention of Pollution from Ships; n.o.s. -

Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect Concentration;

NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading

Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic

Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution

Prevention; PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines

Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure

Activity Relationship; REACH - Regulation (EC) No 1907/2006 of the European

Parliament and of the Council concerning the Registration, Evaluation, Authorisation and

Restriction of Chemicals; RID - Regulations concerning the International Carriage of

Dangerous Goods by Rail; SADT - Self-Accelerating Decomposition Temperature; SDS -

Safety Data Sheet; TCSI - Taiwan Chemical Substance Inventory; TECI - Thailand

Existing Chemicals Inventory; TSCA - Toxic Substances Control Act (United States); UN

- United Nations; UNRTDG - United Nations Recommendations on the Transport of

Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative

Further information

The above information is believed to be correct but does not purport to be all inclusive

and shall be used only as a guide. The information in this document is based on the

present state of our knowledge and is applicable to the product with regard to

appropriate safety precautions. It does not represent any guarantee of the properties of

the product. Sigma-Aldrich Corporation and its Affiliates shall not be held liable for any

damage resulting from handling or from contact with the above product. See

www.sigma-aldrich.com and/or the reverse side of invoice or packing slip for additional

terms and conditions of sale.

for internal use only.

The branding on the header and/or footer of this document may temporarily not visually

match the product purchased as we transition our branding. However, all of the

information in the document regarding the product remains unchanged and matches the

product ordered. For further information please contact till.strobel@mastermix.ag.